In photography and cinematography, multiple exposure is a technique in which the camera shutter is opened more than once to expose the film multiple times, usually to different images. The resulting image contains the subsequent image/s superimposed over the original. The technique is sometimes used as an artistic visual effect and can be used to create ghostly images or to add people and objects to a scene that were not originally there. It is frequently used in photographic hoaxes.( Wiki )
And here are some pretty awesome multiple exposures from Flickr. Most (if not all) of these were done with film.